News

Compositional inhomogeneity in mixed-metal ZIF-8 analogues

Adam’s work on mixed-metal ZIF-8 analogues is out in Chemical Communications!

We study the structural and thermomechanical effects of cation substitution in the compositional family of metal–organic frameworks Zn1−xCdx(mIm)2 (HmIm = 2-methylimidazole). We find complete miscibility for all compositions x, with evidence of inhomogeneous distributions of Cd and Zn that in turn affect framework aperture characteristics. Using variable-temperature X-ray powder diffraction measurements, we show that Cd substitution drives a threefold reduction in the magnitude of thermal expansion behaviour. We interpret this effect in terms of an increased density of negative thermal expansion modes in the more flexible Cd-rich frameworks.

The paper can be found here and the preprint is available for free on ChemRxiv.

Congratulations Adam!

Summer students 2018

Welcome to two undergraduate students, who join the group over the summer: Frank Nightingale and Anisha Bahl, who’ll be working on fundamentals of MOF formation and development of public engagement activities, respectively. They’ve already been hard at work, in the lab, on the 3D printer, making crystallographic models and more…!